1. Tsunade: Tsunade, the leader of the Root organization, is an essential figure in the Leaf Village. Despite his questionable actions, Tsunade's presence strengthens Konoha and makes it the strongest among the Five Great Ninja Villages. As a disciple of the Second Hokage, Tsunade is on par with the Third Hokage in terms of strength. Additionally, he has a skilled team supporting him, making it challenging for Jiraiya to defeat him.

2. Madara Uchiha: Madara, the leader of the Uchiha clan, possesses the strength of a Kage-level ninja. The Uchiha clan's inherent strength and the fact that some members have awakened the Mangekyo Sharingan make Madara a formidable leader.

Having already awakened the Mangekyo Sharingan, Madara can contend with Jiraiya.

3. Hiruzen Sarutobi: Hiruzen, Jiraiya's teacher, demonstrated his formidable strength in battle against Orochimaru. Despite his age, Hiruzen held his own and showed his wisdom and skill. At that time, Hiruzen had the capability to stop Jiraiya.

4. Hiashi Hyuga: Hiashi, the head of the powerful Hyuga clan, may not have a bloodline limit as potent as the Sharingan, but his mastery of the Byakugan surpasses it when used effectively. As the head of the clan, Hiashi is undoubtedly one of the most exceptional Byakugan users.

His proficiency in acupuncture and the Gentle Fist technique gives him an advantage over Jiraiya in close-range combat.

5. Tsunade: Like Jiraiya, Tsunade is one of the three Sannin of Konoha. While her raw power may not match Jiraiya's, her healing techniques and summoning jutsu make her capable of organizing Jiraiya. As a member of the Senju clan and with the power of the slugs, Tsunade can easily withstand Jiraiya's attacks, as seen when she was unfazed by Madara Uchiha's Susanoo arrow.